Ibicuruzwa bisobanura
Uruganda rutunganya ammonia rwatsi rusobanura ikigo gitanga amoniya ikoresheje hydrogène iva mu mazi ya electrolysis (ikoreshwa n’ingufu zishobora kongera ingufu) na azote itandukanijwe n’ikirere, hamwe n’ibikorwa byose bisohoka hafi ya - zero dioxyde de carbone. Ubusanzwe ibicuruzwa biri hejuru ya 99.8%, byujuje ubuziranenge bwinganda nubuhinzi.
Hydrogen Ammonia Plant nigikoresho cyingenzi kuri synthesis ya - ya carbone amoniya, hamwe nubushobozi bwa - ubushobozi buke buva ku gipimo gito - (toni 50 / umwaka) kugirango gikoreshwe gukoreshwa kugeza ku gipimo kinini - (toni 500.000 / umwaka) mu nganda zikoreshwa mu nganda. Ikoreshwa cyane mubice nko gutanga ifumbire, lisansi isukuye, kubika ingufu, hamwe na synthesis.
Icyatsi kibisi cya Amoniya (kizwi kandi nk'ibikoresho bya synthesis ya ammonia ishobora kuvugururwa) ni ibikoresho byuzuye bihuza amazi ya electrolysis, gutandukanya ikirere, hamwe na synthesis ya amoniya ishingiye ku mbaraga zishobora kubaho. Ihame ryibanze ryayo ni ugukoresha amashanyarazi yicyatsi (izuba, umuyaga, hydro, nibindi) kugirango ugabanye amazi muri hydrogène na ogisijeni ukoresheje electrolysis, gutandukanya azote n'umwuka, hanyuma ugereranya ammonia munsi yubushyuhe bwinshi nigitutu binyuze muri Haber - Bosch. Irashobora gutanga umusaruro muke - karuboni ammonia kandi ni ibikoresho nyamukuru byo kwangiza inganda za amoniya.
Ihame ry'akazi
Igikorwa cyuruganda rutunganya ammonia rwatsi rushobora kuvugwa muri make nkintambwe esheshatu zingenzi: gutanga ingufu zamashanyarazi → amashanyarazi electrolysis → hydrogène isuku → gutandukanya ikirere kuri azote → synthesis ya ammonia → kweza ibicuruzwa no kubika
Amashanyarazi ashobora kuvugururwa:Amashanyarazi aturuka ahantu hashobora kuvugururwa (izuba PV, imirasire yumuyaga, nibindi) ihagarikwa binyuze muri sisitemu yo kubika ingufu cyangwa guhuza imiyoboro kugirango itange amashanyarazi ahoraho ya electrolysis y'amazi.
Amazi ya electrolysis:Amazi meza (amazi ya deionised) yinjira muri electrolyzer (alkaline, PEM, cyangwa ubwoko bwa oxyde ikomeye), aho igabanyijemo hydrogène (H₂) na ogisijeni (O₂) munsi yumuriro w'amashanyarazi. Hydrogen isukuye muriki cyiciro ni 99,97% ~ 99,999%.
Isuku rya hydrogen:Hydrogen hydrogène ikomoka kuri electrolysis irasukurwa kandi kugirango ikureho umwanda (nk'ubushuhe, ogisijeni, hamwe nuduce) binyuze mu guhindagurika kwa adsorption (PSA) cyangwa gutandukana kwa membrane, bigera ku bwera burenze cyangwa bungana na 99,999% kugirango wirinde uburozi bwa catalizike muri synthesis.
Gutandukanya ikirere kuri azote:Umwuka wa Atimosifike urahagarikwa, ugakonjeshwa, kandi ukezwa, hanyuma ugatandukanywa na azote yo hejuru - ya azote yera (Iruta cyangwa ingana na 99,999%) ikoresheje distillation ya cryogenic cyangwa gutandukanya membrane, ikuma kandi igashyirwaho ingufu kugirango ikoreshwe.
Sintezike ya Amoniya:Hydrogen isukuye na azote (mu kigereranyo cya 3: 1) byegeranijwe kugeza kuri 15 ~ 30 MPa, bigashyuha kugeza kuri dogere 350 ~ 500, hanyuma bikanyuzwa muri reaction ya synthesis hamwe nicyuma - gishingiye cyangwa rutheniyumu -. Muri ibi bihe, baritabira gukora ammonia (N₂ + 3 H₂ ⇌ 2NH₃), hamwe na - imwe yo gutsinda igipimo cya 10% ~ 20%. Imyuka idakoreshwa irasubirwamo kugirango irusheho gukora neza.
Kweza ibicuruzwa no kubika:Gazi ya synthesis (irimo ~ 15% ammonia) irakonjeshwa kugirango ihuze ammonia mumazi, hanyuma igatandukanywa kandi igasukurwa kuri Greater kuruta cyangwa ingana na 99.8%. Amoniya y'amazi ibikwa mu miyoboro y’umuvuduko (kuri dogere -33 munsi yumuvuduko wikirere cyangwa 1.7 MPa ku bushyuhe bw’ibidukikije) kugirango itwarwe cyangwa ikoreshwe.
Icyatsi kibisi Amoniya Yibyingenzi
Hasi - karubone iramba
Inzira yose ikoresha ingufu zishobora kubaho kandi ikirinda ibicanwa biva mu kirere, bikavamo hafi - zeru za CO₂ (mubisanzwe<0.1 ton CO₂ per ton ammonia, compared to 1.8 ~ 2.8 tons for conventional plants).
01
Ubushobozi bworoshye
Umusaruro umwe - umusaruro uva kuri toni 50 / umwaka (sisitemu ntoya ya modular) kugeza kuri toni 500.000 / mwaka (inganda nini zinganda), uhuza nibisabwa byatanzwe kandi bishyizwe hamwe.
02
Ibicuruzwa byinshi
Amoniya isukuye igera kuri Kurenza cyangwa bingana na 99.8%, hamwe na ultra - amanota meza (Birenze cyangwa bingana na 99,99%) biboneka kubikorwa byihariye (urugero, annealing ya semiconductor).
03
Guhuza ingufu
Irashobora gukora ifatanije na gride yingufu zishobora gukurura kugirango ihindure ihindagurika, ihindure amashanyarazi arenze amoniya nkitwara ingufu.
04
Inzira ndende ikora
Iyo bimaze guhagarara, igihingwa gishobora gukora ubudahwema kumyaka 1 ~ 2, hamwe nigihe cyo guhagarika gahunda yo gusimbuza cataliste no kuyitaho.
05
Ibyiza byibicuruzwa byacu
Mugihe cyo hasi - iterambere rya karubone, igishushanyo mbonera ni ingenzi kuringaniza imikorere no kuramba. Itsinda ryacu ririmo abajenjeri bafite uburambe bwimyaka irenga 25 muri synthesis ya ammonia no kongera ingufu zishobora kongera ingufu, bamenyereye amahame mpuzamahanga nka ISO, ASME, IEC, na REACH. Dutegura ibishushanyo bishingiye kubikenerwa byabakiriya (urugero, ubwoko bwingufu zishobora kongera ingufu, ubushobozi, nubuziranenge) hamwe nuburyo bwaho (urugero, ikirere, ituze rya gride), guhuza electrolyzer - catalizator ihuza, sisitemu yo kugarura ubushyuhe, hamwe nigipimo cyo kongera ingufu za gaze kugirango twongere ingufu zingufu (mubisanzwe Birarenze cyangwa bingana na 55% LHV kuva mumashanyarazi kugeza kuri amoniya). Twirinda inyandikorugero zisanzwe, tukemeza ko buri gihingwa gihuza intego zihariye za decarbonisation.
Dushyira mubikorwa byimazeyo ISO9001 na ISO14001 mugihe cyubuzima bwumushinga, gikubiyemo igishushanyo, amasoko, ubwubatsi, na komisiyo. Mu cyiciro cyo gushushanya, kwigana inzira bigenzura imikorere n'umutekano; ibice byingenzi (electrolyzers, compressor, catalizator) biva mubatanga ibyemezo kandi bigakorerwa igenzura rikomeye; ubwubatsi bukurikira SOPs nziza, hamwe na weld ikomeye hamwe nubwato bwumuvuduko bugenzurwa hakoreshejwe UT, RT, hamwe na hydrostatike; komisiyo ikubiyemo 100 - isaha ikomeza gukora ibizamini kugirango yemeze umusaruro, ubuziranenge, hamwe n’ibyuka bihumanya. Ubu buryo butunganijwe butuma ubuziranenge buhoraho no gutanga ku gihe.
Dushyira imbere ubuziranenge nkibanze shingiro rya - kwizerwa rya karubone. Buri gihingwa gikorerwa ibizamini byinshi -: gukora electrolyzer ikora mumitwaro itandukanye, kugumya ibikorwa bya catalizator kumasaha arenga 1.000, hamwe na synthesis loop ihindagurika mugihe ihindagurika ryumuvuduko. Ibice byingenzi (urugero, PEM electrolyzer stacks) bifite ubuzima bwa serivisi burenze cyangwa bungana namasaha 60.000, kandi catalizator (ruthenium - ishingiye) ikomeza Ibikorwa birenze cyangwa bingana na 80% mubikorwa byimyaka 5 ~ 8. Turemeza ko igihingwa kiboneka kirenze cyangwa kingana na 90% (usibye kubungabunga) kandi tugatanga ibyemezo byubuziranenge byuzuye, hamwe nu ruganda rwujuje ibyangombwa 100%.
Serivise nziza itanga umusaruro muke - umusaruro wa karubone. Iyo twakiriye icyifuzo cya serivisi, itsinda ryacu rya tekinike ritanga ibitekerezo byambere mugihe cyamasaha 12 (24/7) ukoresheje terefone, imeri, cyangwa videwo. Kubibazo bya kure - ibibazo byakemuka (urugero, guhindura ibipimo ngenderwaho), turayobora gukemura mumasaha 48; kuberako kuri - ikeneye urubuga, injeniyeri zoherejwe mumasaha 72 (murugo) cyangwa iminsi 5 (mpuzamahanga). Turatanga kandi gahunda yo kubungabunga ibidukikije hamwe na serivise zo gusimbuza catalizike kugirango tugabanye igihe gito.
Ibihingwa byacu byizewe ninganda ziyobora mumirenge ya - ya karubone, harimo ifumbire, ingufu zishobora kongera ingufu, kubika ingufu hamwe n’ubuhinzi-mwimerere, byerekana kwizerwa mubikorwa binini -.
Dutanga uburyo bwinshi bwubufatanye: kugurisha ibikoresho (imishinga ya turnkey), imishinga ihuriweho (ishoramari nigikorwa gisangiwe), hamwe namasezerano yo gutanga amoniya (dufite kandi dukora inganda, kugurisha amoniya kubiciro byumvikanyweho). Ibi bituma abakiriya bahitamo bashingiye ku mari shingiro, ubushobozi bwa tekiniki, hamwe ningamba ndende -.
Kugereranya uburyo butandukanye bwo gukora amoniya
|
Uburyo bwo gukora Amoniya |
Amahame remezo |
Ibyiza |
Ibikurikizwa |
|
Uruganda rutunganya ammonia rwatsi |
Kuvugururwa - ikoreshwa na electrolysis + Haber - Synthesis ya Bosch |
Hafi ya - zeru zangiza, ibikoresho bibisi biramba |
Hasi - ifumbire ya karubone, lisansi yicyatsi, kubika ingufu |
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Igiti gisanzwe cya ammonia (imvi zijimye) |
Gazi isanzwe ivugurura hydrogene + Haber - Synthesis ya Bosch |
Ikoranabuhanga rikuze, igiciro cyo hejuru |
Kinini - igipimo cya ammonia yinganda (ifumbire gakondo, imiti) |
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Igihingwa cya ammonia yubururu |
Icyatsi cya ammonia + gufata karubone no kubika (CCS) |
Ibyuka bihumanya kurusha ammonia yumukara, ikoresha ibikorwa remezo bihari |
Inzibacyuho yo hasi - karuboni ammonia (kubyara ingufu, lisansi yoherejwe) |
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Umusemburo wibinyabuzima |
Microbial azote ikosora (urugero, cyanobacteria) |
Ibihe bishya, byoroheje |
Gitoya - igipimo, ammonia yihariye (ubuhinzi-mwimerere, ibinyabuzima) |
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Amashanyarazi ya amoniya yamashanyarazi |
Bayobora N₂ + H₂O electrolysis kuri NH₃ |
Inzira yoroshye, ibidukikije |
Ikoranabuhanga rishya (R&D, niche progaramu) |
Ibirangantego: uruganda rutunganya amoniya rwatsi, Ubushinwa uruganda rukora ammonia rwatsi, abatanga isoko, uruganda